A Solid State \u3csup\u3e13\u3c/sup\u3eC-NMR Study of Diamonds and Graphites

The 13C-NMR spectra of gem quality and industrial diamonds show two resonances with the more intense resonance at high field. Two resonances are also shown in 13C-NMR spectra of various graphites; however, the low field resonance is of greater intensity than the high field resonance in the graphites. The resonances are very broad and they are assigned to graphite type (sp2) carbon and diamond type (sp3) carbon

Mechanism for potential strengthening of Atlantic overturning prior to collapse

The Atlantic meridional overturning circulation (AMOC) carries large amounts of heat into the North Atlantic influencing climate regionally as well as globally. Palaeo-records and simulations with comprehensive climate models suggest that the positive salt-advection feedback may yield a threshold behaviour of the system. That is to say that beyond a certain amount of freshwater flux into the North Atlantic, no meridional overturning circulation can be sustained. Concepts of monitoring the AMOC and identifying its vicinity to the threshold rely on the fact that the volume flux defining the AMOC will be reduced when approaching the threshold. Here we advance conceptual models that have been used in a paradigmatic way to understand the AMOC, by introducing a density-dependent parameterization for the Southern Ocean eddies. This additional degree of freedom uncovers a mechanism by which the AMOC can increase with additional freshwater flux into the North Atlantic, before it reaches the threshold and collapses: an AMOC that is mainly wind-driven will have a constant upwelling as long as the Southern Ocean winds do not change significantly. The downward transport of tracers occurs either in the northern sinking regions or through Southern Ocean eddies. If freshwater is transported, either atmospherically or via horizontal gyres, from the low to high latitudes, this would reduce the eddy transport and by continuity increase the northern sinking which defines the AMOC until a threshold is reached at which the AMOC cannot be sustained. If dominant in the real ocean this mechanism would have significant consequences for monitoring the AMOC

X-ray bright active galactic nuclei in massive galaxy clusters III: New insights into the triggering mechanisms of cluster AGN

We present the results of a new analysis of the X-ray selected Active Galactic Nuclei (AGN) population in the vicinity of 135 of the most massive galaxy clusters in the redshift range of 0.2 < z < 0.9 observed with Chandra. With a sample of more than 11,000 X-ray point sources, we are able to measure, for the first time, evidence for evolution in the cluster AGN population beyond the expected evolution of field AGN. Our analysis shows that overall number density of cluster AGN scales with the cluster mass as $\sim M_{500}^{-1.2}$. There is no evidence for the overall number density of cluster member X-ray AGN depending on the cluster redshift in a manner different than field AGN, nor there is any evidence that the spatial distribution of cluster AGN (given in units of the cluster overdensity radius r_500) strongly depends on the cluster mass or redshift. The $M^{-1.2 \pm 0.7}$ scaling relation we measure is consistent with theoretical predictions of the galaxy merger rate in clusters, which is expected to scale with the cluster velocity dispersion, $\sigma$, as $\sim \sigma^{-3}$ or $\sim M^{-1}$. This consistency suggests that AGN in clusters may be predominantly triggered by galaxy mergers, a result that is further corroborated by visual inspection of Hubble images for 23 spectroscopically confirmed cluster member AGN in our sample. A merger-driven scenario for the triggering of X-ray AGN is not strongly favored by studies of field galaxies, however, suggesting that different mechanisms may be primarily responsible for the triggering of cluster and field X-ray AGN.Comment: 21 Pages, 8 figures, 5 tables. Submitted to MNRAS. Comments are welcome, and please request Steven Ehlert for higher resolution figure

X-ray Bright Active Galactic Nuclei in Massive Galaxy Clusters II: The Fraction of Galaxies Hosting Active Nuclei

We present a measurement of the fraction of cluster galaxies hosting X-ray bright Active Galactic Nuclei (AGN) as a function of clustercentric distance scaled in units of $r_{500}$. Our analysis employs high quality Chandra X-ray and Subaru optical imaging for 42 massive X-ray selected galaxy cluster fields spanning the redshift range of $0.2 < z < 0.7$. In total, our study involves 176 AGN with bright ($R <23$) optical counterparts above a $0.5-8.0$ keV flux limit of $10^{-14} \rm{erg} \ \rm{cm}^{-2} \ \rm{s}^{-1}$. When excluding central dominant galaxies from the calculation, we measure a cluster-galaxy AGN fraction in the central regions of the clusters that is $\sim 3$ times lower that the field value. This fraction increases with clustercentric distance before becoming consistent with the field at $\sim 2.5 r_{500}$. Our data exhibit similar radial trends to those observed for star formation and optically selected AGN in cluster member galaxies, both of which are also suppressed near cluster centers to a comparable extent. These results strongly support the idea that X-ray AGN activity and strong star formation are linked through their common dependence on available reservoirs of cold gas.Comment: 9 Pages, 4 Figures, accepted for publication in MNRAS, please contact Steven Ehlert ([email protected]) with any querie

Probing the extreme realm of AGN feedback in the massive galaxy cluster, RX J1532.9+3021

We present a detailed Chandra, XMM-Newton, VLA and HST analysis of one of the strongest cool core clusters known, RX J1532.9+3021 (z=0.3613). Using new, deep 90 ks Chandra observations, we confirm the presence of a western X-ray cavity or bubble, and report on a newly discovered eastern X-ray cavity. The total mechanical power associated with these AGN-driven outflows is (22+/-9)*10^44 erg/s, and is sufficient to offset the cooling, indicating that AGN feedback still provides a viable solution to the cooling flow problem even in the strongest cool core clusters. Based on the distribution of the optical filaments, as well as a jet-like structure seen in the 325 MHz VLA radio map, we suggest that the cluster harbours older outflows along the north to south direction. The jet of the central AGN is therefore either precessing or sloshing-induced motions have caused the outflows to change directions. There are also hints of an X-ray depression to the north aligned with the 325 MHz jet-like structure, which might represent the highest redshift ghost cavity discovered to date. We further find evidence of a cold front (r=65kpc) that coincides with the outermost edge of the western X-ray cavity and the edge of the radio mini-halo. The common location of the cold front with the edge of the radio mini-halo supports the idea that the latter originates from electrons being reaccelerated due to sloshing induced turbulence. Alternatively, its coexistence with the edge of the X-ray cavity may be due to cool gas being dragged out by the outburst. We confirm that the central AGN is highly sub-Eddington and conclude that a >10^10M_Sun or a rapidly spinning black hole is favoured to explain both the radiative-inefficiency of the AGN and the powerful X-ray cavities.Comment: Accepted for publication to ApJ (minor corrections), 16 pages, 16 figures, 5 tables. Full resolution at http://www.stanford.edu/~juliehl/M1532

The Effect of a Reduction in Phosphate Application on Soil Phosphate Pools

Excessive use of manure and fertilisers in western Europe has led to high phosphorus (P) contents in many agricultural soils leading to environmental P losses by overland flow, subsurface drainage and leaching to groundwater. To stop phosphate build up in the soil and leaching to surface and ground waters, the Dutch government is gradually reducing allowable phosphate application on grassland from 130 kg/ha per year in 2005 to 90 kg/ha per year in 2015. This will lead to a reduction of the phosphate surplus from 40 in 2005 to 0 kg/ha per year. To investigate the impact of reductions in application rates on soil phosphate, leaching and grass production, a field experiment was started in 1997 on four dairy farms on two sandy soils, a peat and a clay soil

Psychologische Prädiktoren für das Auftreten einer Major Depression und einer PTBS nach schweren Unfällen

Theoretischer Hintergrund/Fragestellung: Ziel unserer prospektiven Studie war die Identifikation von Prädiktoren für das Auftreten einer Depression im ersten halben Jahr nach einem Unfall. Methode: Es wurden 52 Unfallpatienten untersucht. Die Ersterhebung erfolgte innerhalb der ersten sechs Wochen nach dem Unfall. Ergebnisse: Depressive Patienten gaben kurz nach dem Unfall eine geringere Lebenszufriedenheit und soziale Unterstützung an und berichteten häufiger über psychische Störungen und traumatische Erlebnisse vor dem Unfall als Nicht-Depressive. Außerdem litten sie zum Zeitpunkt der Ersterhebung häufiger unter psychischen Störungen und fühlten sich durch die psychischen Symptome stärker beeinträchtigt. Schlussfolgerung: Die Ergebnisse legen nahe, dass Patienten mit einem Risiko für die Entwicklung einer Depression bereits kurz nach einem Unfall identifiziert werden können